{"created":"2024-08-07T23:54:21.717846+00:00","id":2000527,"links":{},"metadata":{"_buckets":{"deposit":"37b7359f-0dbf-452c-b7d4-87403d92dd55"},"_deposit":{"created_by":11,"id":"2000527","owners":[11],"pid":{"revision_id":0,"type":"depid","value":"2000527"},"status":"published"},"_oai":{"id":"oai:usp.repo.nii.ac.jp:02000527","sets":["1719360431479:1719360490713:1722998947419"]},"author_link":[],"item_1617186331708":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"植物油の交差メタセシス変換による炭化水素燃料基材の選択的生成","subitem_title_language":"ja"}]},"item_1617186385884":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Selective formation of hydrocarbon fuel substrates by cross-metathesis conversion of vegetable oils","subitem_alternative_title_language":"en"}]},"item_1617186419668":{"attribute_name":"研究代表者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"山根, 浩二","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"295_ja.html","nameIdentifierScheme":"滋賀県立大学研究者総覧","nameIdentifierURI":"https://db.spins.usp.ac.jp/html/295_ja.html"}]}]},"item_1617186609386":{"attribute_name":"主題","attribute_value_mlt":[{"subitem_subject":"バイオ炭化水素燃料","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"オレフィンメタセシス変換","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"量子化学","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"バイオ燃料","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"メタセシス反応","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"量子化学計算","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"メタセシス","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"トリグリセリド","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"炭化水素","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"不飽和脂肪酸","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"オレフィン","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"交差メタセシス反応","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"炭化水素燃料","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"植物油","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"脂肪酸メチルエステル","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"交差メタセシス変換","subitem_subject_language":"ja","subitem_subject_scheme":"Other"}]},"item_1617186626617":{"attribute_name":"研究課題番号","attribute_value_mlt":[{"subitem_description":"20K04333","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_1617186702042":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_1719208003433":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_1719208060448":{"attribute_name":"報告年度","attribute_value_mlt":[{"subitem_date_issued_datetime":"2022","subitem_date_issued_type":"Issued"}]},"item_1719375495957":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_1720761294142":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"科学研究費助成事業データベース"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-20K04333/","subitem_relation_type_select":"URI"}}]},"item_1724117245127":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"本研究では、植物油の交差メタセシス反応によって、任意の炭化水素燃料基材を選択的に得ることを最終目標としている。まず、第一段階として反応物である植物油を構成する脂肪酸とオレフィンとの組み合わせにより、どのような組成の生成物が得られるのかを明らかにするため、単一組成の脂肪酸メチルエステルFAMEとオレフィンとのメタセシス反応実験をおこなった。　つぎに、不飽和度の高いトリグリセリド成分で構成されているアマニ油と１－オクテンを用いて、Grubbs触媒を介した交差メタセシス変換反応実験を行った。その結果、炭素数Ｃ７の炭化水素成分が多く生成することを見出した。","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"The objective of this study is to selectively obtain an arbitrary hydrocarbon base material from vegetable oil, a triglyceride, using a cross-metathesis reaction with olefins. In this paper, the effects of the number of unsaturated double bonds, the number of olefin carbons, and the position of carbon double bonds in the vegetable oils used as reactants on the composition of the hydrocarbons produced were investigated. As a result, it was found that the higher the number of unsaturated double bonds, the lighter the hydrocarbon base material is.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_title":"植物油の交差メタセシス変換による炭化水素燃料基材の選択的生成","item_type_id":"40014","owner":"11","path":["1722998947419"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-07-31"},"publish_date":"2023-07-31","publish_status":"0","recid":"2000527","relation_version_is_last":true,"title":["植物油の交差メタセシス変換による炭化水素燃料基材の選択的生成"],"weko_creator_id":"11","weko_shared_id":-1},"updated":"2024-08-20T05:36:50.839458+00:00"}